Konami are starting an anime distribution service on the PlayStation Network for anime series based on their core franchises in Japan, the company revealed earlier this week. The first series to be rolled out via the service will Tokimeki Memorial OnlyLove .
I'm kind of bummed that all you can do is rent stuff rather than own it. That's a big problem with Anime on the PSN for me, the fact that an episode can be around 4 USD (i.e Xam'd) but you can only rent it and not own it =/
Still, its a step in the right direction I guess XD